High activity acetylene polymerisation with a bis(imino)pyridine iron(II) catalyst.

نویسندگان

  • Samuel S Karpiniec
  • David S McGuinness
  • George J P Britovsek
  • Tanita S Wierenga
  • Jim Patel
چکیده

A catalyst system composed of a 2,6-bis(arylimino)pyridineiron(II) dichloride complex and methylaluminoxane is found to be extremely active for acetylene polymerisation. The formation of poly(acetylene) gels and surface films occurs at very low catalyst concentrations, around three orders of magnitude lower than traditional catalyst systems.

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عنوان ژورنال:
  • Chemical communications

دوره 47 24  شماره 

صفحات  -

تاریخ انتشار 2011